It is chlorophyll which gives the leaves their green colour. This chemical absorbs energy from sunlight which it uses to transform carbon dioxide and water into carbohydrates like sugars and starch.
Along with this green pigment are also yellow to orange pigments, carotenes and xanthophyll, which, for most of the year, are masked by the greater amounts of green.
In autumn, due to changes in the length of daylight and in temperature, the leaves cease the food-making process. The chlorophyll then breaks down, the green colour disappears and the yellow to orange colours become visible.
At the same time other chemical changes can occur forming additional colours through the development of red anthocyanin pigments.
Some mixtures give rise to the reddish and purplish colours while others express orange.
In other words all the different colours are due to the mixing of varying amounts of chlorophyll residue and other pigments in the leaf during the season.
This is called abscission. This is a fascinating and complex process. More information here.
Grapevines are one of these.
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